| RESPONSE
STRATEGIES AND CONSIDERATIONS |
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| This
document contains information on Response Strategies and Considerations,
including: Environmental Considerations; Strategies
of Oil Spill Response; Chemicals and Their Use;
and Fate and Effects of Spilled Oil.
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Because human error causes 46% of oil spills and equipment failure
34% the first strategy must be that of PREVENTION. However, assuming
that in the particular case prevention has not been effective the
remaining strategic options are: |
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| Contain
and Recover |
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| Containment
and Recovery removes the pollutant from the environment by mechanical
means. This strategy has the following characteristics: |
- High
Capital Investment
- Need
for Logistics Support
- Effectiveness
Sharply Impacted by Weather
- Encounter
Rate Very Important
- Need
for Disposal
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The usual method of containment and recovery involves deploying
booms to prevent the oil from spreading and to concentrate it. Skimmers
are then used to recover the concentrated oil. It is then transferred
to temporary storage and eventually to a permanent storage/treatment
facility. When employing this strategy it is necessary to consider
the following questions: |
- Can
the operation be mounted close to the source of the spill so
that the spread of oil can be contained?
- Can
sufficient vessels be mobilized to operate the appropriate numbers
and types of booms and skimmers?
- Are
vessels with adequate onboard oil storage capacity available?
- Will
weather conditions permit the equipment to be used effectively,
if at all?
- Is the
type and condition of the oil amenable to mechanical recovery?
- Are
the required number of trained equipment operators and maintenance
personnel available?
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Dispersion |
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| Natural
Dispersion - When a great deal of mixing energy is applied
at the oil-water interface, i.e. such as a rough sea surface, the
oil and water becomes emulsified and may disperse naturally. |
| Dispersant
- Using a dispersant as a strategy involves the use of chemicals
to speed up the process of natural dispersion. FEDERAL AUTHORIZATION
MUST BE OBTAINED IN EACH CASE BEFORE THE USE OF DISPERSANTS. Dispersants
act in the same way as household detergents; when they are added
to a film of oil on the surface of the water the oil breaks up into
very small droplets forming thin emulsions which disperse in the
water column. In effect, they speed up the natural processes of
dispersion. In dispersed form the oil is subject to degradation
by micro-organisms which occur naturally in the sea. A characteristic
plume can be seen spreading slowly down the water surface shortly
after treatment if an oil has been satisfactorily dispersed. Dispersants
do not destroy the oil. However, this must be weighed against the
fact that dispersing the oil in the water column makes its toxic
components more readily available to marine organisms, particularly
in shallow water. Dispersants
do not work on all types of oil or in cold weather conditions
under which oil tends to become very viscous. Evaporation and
emulsification which render oil resistant to dispersant occur
over time and in most cases, dispersant will likely be ineffective
after a day or two. If the oil is very viscous (thick) dispersants
are ineffective, since they tend to run off the oil into the water
before they can penetrate. As a general rule, dispersants can
be effective in dispersing most liquid oils and liquid water-in-oil
emulsions with viscosities less than about 2000 centistokes. Oils
that may be more susceptible to treatment on first entry to the
water become progressively less so as mousse forms or weathering
takes place. |
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There are several Dispersant application methods:
- Hand
application (sprayer)
- By aircraft
spray system (for example ADDS Pack)
- By spray
systems installed on ships and boats
The method
of application depends primarily on the type of dispersant, the
size and location of the spill, and the availability of vessels
or aircraft for spraying the dispersant. You might want to take
a look at drawings of some
of the various dispersant application systems. (Note: This
page has several large graphics and will take a while to load.)
For a
dispersant application to be effective several factors in addition
to the type of dispersant being used need to be considered because
they control the dispersant to oil application ratio; the vessel
or aircraft speed, the swath width (path covered by the spray
pattern), the size and number of the spray nozzles, and the thickness
of the oil.
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| In-situ
Burn |
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| In-situ
Burning involves igniting the oil on the surface of the water works
well in removing large quantities of spilled oil from the water.
To be successful, this is a strategy best initiated early prior
to evaporation of the lighter ends which support combustion and
prior to weathering of the oil.
In-situ burning can only be done in open waters where no danger
is posed to drilling rigs, ships, or shoreline.
Fire boom is used to corral the oil and contain it during
the burn. Obviously some air pollution does occur when oil is
burned.
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Do Nothing |
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| To
Do Nothing is a strategy seldom used and is difficult to justify.
However, this strategy may sometimes be appropriate. No action is
taken except for monitoring the movement of the spilled oil. Natural
and biological processes will disperse most spills given time. Crude
oils, particularly of the lighter kinds, that have been spilled
a considerable distance offshore in the rough conditions characteristic
of those waters are unlikely to pose an environmental threat unless
in close proximity to vulnerable concentrations of sea birds. There
is a likelihood that these oils will be dispersed by natural processes
before reaching shore. |
| Beach
Clean-Up |
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| Beach
Clean-up. In some cases, despite all the efforts to deal with spilled
oil offshore, some oil still reaches the shore. Or it may be an
acceptable strategy depending upon the circumstances to allow the
oil to come ashore for subsequent collection. In these instances
the principal means of cleaning up the oil becomes physical. Beach
clean up is labor intensive. The tools used include buckets, shovels,
skimmers, booms, earth moving equipment, pumps, vacuum equipment,
absorbents, and temporary storage. If the beach has not been cleaned
prior to oil impact, oiled debris must be disposed of along with
oil and oiled sand. |
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| CHEMICALS
AND THEIR USE |
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Chemicals used to treat oil spills
include the following:
- Dispersants.
Dispersants contain chemicals which reduce the surface tension
between oil and water. They therefore result in breakup and
dispersal of an oil slick throughout the water column.
- Emulsion
Breakers. Used to break down the water/oil mixture which develops
as oil weathers. This mixture, called mousse, is around 80%
water and is very difficult to skim, pump, or separate.
- Gelling
Agents. These are chemicals which increase the viscosity of
the oil slick. They therefore reduce its rate of spread on the
surface of the water.
- Herders.
Also called collecting agents. Herders work by affecting the
surface tension of the oil and cause the oil to herd to a collection
point.
- Viscoelastic
Additives. Include Solidifying Agents and Gelling Agents. They
convert liquid oil into a solid form, thereby facilitating recovery
by manual means or nets. Gelling agents increase the viscosity
of the oil slick and thereby reduce its rate of spread. These
agents are rarely used because the quantity required to gel
an oil are extremely high in relation to the volume of oil and
it may take as long as 8 hours before the gel is strong enough
to allow recovery.
- Bioremediation
Chemicals. These are biological agents. They are a combination
of enzymes, natural organisms and nutrients which increase the
rate of natural degradation of oil. This is a long term technique
because it may take months and years to be effective.
- Burning
Agents. Burning agents are substances that make it possible
to ignite oil on the water or upon the shoreline. Getting oil
on water to burn is often very difficult. Typical examples of
burning agents are gasoline and light crude oils.
- Neutralizing
Agents. These are used to treat spilled oil and they work by
reacting chemically with the oil to form less harmful substances.
- Sinking
Agents. These are special materials applied to the oil which
adsorb the oil to their surface. This combination of oil and
the sinking agent is heavier than water and sinks.
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